A note on the Hydrogen spectrum

The emission spectrum of atomic hydrogen is given by this amazing spectral series diagram:

image

Let’s take a closer look at only the visible portion of the spectrum i.e the Balmer series.

image

If a hydrogen lamp and a diffraction grating just happen to be with you, you can take a look at the hydrogen lamp through the diffraction grating, these lines are what you would see:

image

Source

These are known emission lines and they occur when the hydrogen atoms in the lamp return to a state of lower energy from an excited energy state.

image

           Representation of emission and absorption using the Bohr’s model

Here’s another scenario that could also happen:

image

You have a bright source of light with a continuous spectrum and in between the source and the screen, you introduce a gas (here, sodium)

image

Source: Harvard Natural sciences

The gas absorbs light at particular frequencies and therefore we get dark lines in the spectrum.

This is known as absorption line. The following diagram summarizes what was told thus-far in a single image:

image

The absorption and emission spectrum for hydrogen look like so :

image

Stars and Hydrogen

One of the comments from the previous post was to show raw spectrum data of what was being presented to get a better visual aid.

Therefore,the following spectrum is a spectrum of a star taken from the Sloan Digital Sky Survey (SDSS)

image

                                 Plot of wavelength vs median-flux

Here’s the spectrum with all the absorption lines labelled:

image

Source: SDSS

You can clearly see the Balmer series of hydrogen beautifully encoded in this spectrum that was taken from a star that is light-years away.

And astronomers learn to grow and love these lines and identify them immediately in any spectrum, for they give you crucial information about the nature of the star, its age, its composition and so much more.

image

Source: xkcd

Have a great day!

*If you squint your eyes a bit more you can find other absorption lines from other atoms embedded in the spectrum as well.

Advertisement

On the strong 5577Å spectrum line


The above is a plot of the Wavelength(in Å) in the x-axis vs the flux of some objects from the Sloan digital survey ( consists of galaxies, young stars, Quasars, etc)

But  there is one strong peak in all of those plots that seems to stand out: 5577 Å

image

And if you like, the color that it represents is the above  (Made with Stanford’s color matcher app)

A nightmare for the astronomer

image

This line at 5577.338 is what astronomers refer to as a ‘skyline emission’ or a ‘mesospheric night-glow’ and arises from the recombination of atomic oxygen in the mesosphere.[2]

image

                                               Source

This line is of no significance to an astronomer who is looking to find out properties about a far away astronomical object. Yet, this line pops up in every spectrum of any object that you look at in outerspace!

In addition since the line is so strong, it contaminates the nearby pixels making the nearby data unusable and also messes up the scaling of the plot.

image

Example of contaminated pixel columns in an image because of bright object

Wavelength Calibration

What do you do with something that is always there but has no use for you? – Re-purpose it!

image

Having noticed that this peak was consistent at 5577.338, Astronomers decided that they would use this peak line in the data as a reference to calibrate their actual data. (known as ‘zero-point correction’).

This ensures that all the spectrum lines in the data are aligned and any errors that might have occurred during observation are corrected for.

Other lines ?

There are other lines at 6300,6363, etc which are sometimes as bright or brighter than the 5577 line that are also used for calibration.

If you are interested in learning more, the following are three papers that this post was inspired from and they dive deeper into more technical details that underlie this fascinating topic:

[1] Night-Sky High-Resolution Spectral Atlas of OH and O2 Emission Lines for Echelle Spectrograph Wavelength Calibration

[2] Mesospheric nightglow spectral survey taken by the ISO Spectral Spatial Imager on ATLAS 1

[3] Variability of the mesospheric nightglow sodium D2/D1 ratio

Have a great day!

This is the visible spectrum of the light from the sun. And if you have played with white light and prisms before, it might come as a huge surprise to you to know that the spectrum from the sun is actually not continuous.

image

Why is it not ? The dark patches in the above spectrum arise from gas at or above the
Sun’s surface absorbing sunlight emitted below.

image

                                               Source

Since there are different types of gases that compose the sun, there are numerous wavelengths of light that get absorbed by these gases.

image

                                         Source: xkcd

How do we know which line corresponds to which ? Well, it’s because we have a periodic table, and we know the spectrum of all the elements in it:

image

                                               Source

And then it’s a matter of solving the jigsaw puzzle of fitting the spectrum with the tiles that you have. When we do so, we obtain the following composition of elements:

image

                                   Source: Earth Blog

We can even take it one step further by finding the composition of other neighboring stars as well.

image

                                  Source: Potsdam University 

All of this information about the star can be captured from a simple spectrum. And this is why one of the most important tool that an astronomer has about an object is it’s spectrum.

Have a good one!

LED + Liquid Nitrogen = Mind Blown!

This GIF is probably one of the most pristine ways to demonstrate the effect of changing the bandgap in a semiconductor.

When the electrons have to go from the n-type layer to the p-type layer, they have to lose energy. And this energy is imparted as photons. That’s how the LED works.

image

                                                     Source 

Since the LED is now immersed in liquid nitrogen, the band gap ( the difference in energy between the n-type and p-type layers ) has increased.

And therefore the energy of the light emitted is also increased. Orange( Lower energy ) – > Green ( Higher Energy ).

image

                                                   Source

Pretty cool eh ?

Why does the bandgap depend on temperature ?